Application of Magnesium Oxide in Electromagnetic Shielding Materials

Messi Biology states that the application of magnesium oxide (MgO) in the field of electromagnetic shielding has been upgraded from an “auxiliary filler” to a core functional layer characterized by high dielectric constant, low loss, light weight, and multi-spectrum compatibility. With its comprehensive advantages of “high dielectric constant, low loss, light weight, and low cost,” magnesium oxide is becoming the next-generation core material for electromagnetic shielding, from consumer electronics to defense equipment.

Electromagnetic Shielding Materials

01 Shielding Mechanism: High Dielectric Constant + Multipolarization Loss

  • A high εr (≈9.8) enables magnesium oxide to generate strong interfacial polarization and dielectric loss for incident electromagnetic waves.
  • Nanoscale defects and surface dipoles further introduce relaxation polarization, achieving a reflection loss of over –20dB within the 1–40GHz range, with a shielding efficiency of ≥99%.

02 Material Forms: From “Powder Filler” to “Multilayer Metamaterial”

  • Coating Form: Nano-magnesium oxide is dispersed in a silicone-acrylic resin and sprayed to form a dense coating of 80–120µm. It can be used for 5G base station enclosures and automotive radar, with a shielding effectiveness of 45–60dB.
  • Composite Structure: By blending with CNTs, MXenes, or Ag nanowires, a “conductive-dielectric” dual network is formed, which provides both EMI shielding and flexibility, with performance degradation of less than 5% after 1000 bending cycles.
  • Multilayer Design: MgO layers with different particle sizes/orientations are arranged in a frequency gradient to achieve broadband adaptive shielding from 2–18GHz.

03 Environmental and Process Advantages

  • Harsh Environment Resistance: Magnesium oxide has a melting point of 2852℃ and maintains its shielding performance in environments ranging from –55℃ to 200℃, as well as in high humidity and salt spray conditions.
  • Low-Temperature Curing: It can be cured and molded at 80–120℃, making it fully compatible with existing processes for PCBs and plastic enclosures without the need for high-temperature sintering.

Future Trends

  • Nanoporous Magnesium Oxide: With a pore size of 50–200nm, it will be used for millimeter-wave/terahertz integrated shielding films, with a target thickness of <50µm and a shielding effectiveness of >50dB.
  • Tunable Shielding: By regulating the surface charge density of magnesium oxide through electric fields or temperature, a tunable shielding window can be achieved to meet the dynamic spectrum requirements of 6G.
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