The Moisture Absorption Mechanism of Magnesium Oxide as a Desiccant

Magnesium oxide (MgO), due to its unique physical and chemical properties, is widely used as a highly efficient desiccant in industrial and packaging fields. Its moisture absorption mechanism differs from traditional physical adsorption desiccants, belonging instead to a chemical absorption reaction. This gives it stronger moisture absorption capacity and a more lasting drying effect.

Magnesium Oxide as a Desiccant

1. Moisture Absorption Reaction Principle

When magnesium oxide absorbs water, the following reaction occurs:

MgO + H₂O → Mg(OH)₂

This reaction is an endothermic chemical reaction. The magnesium hydroxide produced after the reaction is stable and non-volatile, ensuring that the desiccant will not “rewet” or liquefy after absorbing moisture. This makes it suitable for application scenarios with strict environmental requirements.

2. Structural Characteristics Aid Moisture Absorption Performance

  • Magnesium oxide is a porous material with a large specific surface area;
  • There are a large number of active sites in its crystal structure, especially unsaturated oxygen ions, which easily form hydrogen bonds with water molecules;
  • These structural characteristics enable it to quickly capture and bind water molecules from the air.

3. Advantages of Chemical Moisture Absorption

  • Strong Moisture Absorption Capacity in High-Humidity Environments: Unlike physical adsorption desiccants which easily saturate in high-humidity environments, MgO can still continuously absorb water at high humidity;
  • No Corrosivity and Liquefaction Risk: The magnesium hydroxide produced by moisture absorption is solid, posing no leakage risk;
  • Good Thermal Stability: It can maintain structural stability even in high-temperature environments and will not degrade or lose efficacy.

4. Strong Environmental Adaptability

  • Can be applied in various fields, such as electronic components, pharmaceutical packaging, instruments and meters, etc.;
  • Does not rely on extremely tightly sealed packaging environments, making it suitable for placement under complex transportation or storage conditions.
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