The Whitening Effect of Magnesium Carbonate in Ceramic Glazes

Messi Biology states that ceramic art is one of the oldest forms of human civilization’s creation, while modern high-grade ceramic manufacturing elevates this art to a new pinnacle where science and technology are perfectly integrated. Whether it’s the warm, jade-like bone china tableware or the mirror-smooth high-end sanitary ware, their stunning visual appeal is largely due to the perfect glaze layer on their surface. In the formulation of this “snow-white garment,” magnesium carbonate plays a vital role, acting as both an excellent mineralizer and a highly effective whitening agent, silently safeguarding the whiteness and luster of high-grade ceramics.

Ceramic Glazes

The mechanism of action of magnesium carbonate in ceramic glazes is a complex and intricate process. When the glaze undergoes high-temperature firing in the kiln, magnesium carbonate decomposes, forming active magnesium oxide (MgO) and releasing carbon dioxide. The newly formed magnesium oxide immediately integrates into the developing glassy glaze layer, a process that brings multiple benefits: Firstly, as a strong flux, magnesium oxide effectively lowers the melting temperature of the glaze, promoting thorough melting and homogenization of the glaze components, resulting in a denser, smoother glassy glaze structure with higher surface hardness and luster. Secondly, magnesium oxide can adjust the thermal expansion coefficient of the glaze, allowing it to better match the thermal expansion properties of the ceramic body; this characteristic significantly reduces defects such as cracking and glaze peeling caused by uneven stress during product cooling, improving the yield rate.

Most importantly is its whitening effect. Ceramic raw materials inevitably contain trace amounts of coloring oxide impurities such as iron (Fe) and titanium (Ti), which can cause the glaze surface to exhibit an undesirable pale yellowish tint. The introduction of magnesium oxide can form specific crystalline phases (such as cordierite, spinel, etc.) with components like silicon and aluminum in the glaze, these phases possessing high whiteness and refractive index. This effectively “dilutes” and “masks” the color manifestation of impurity ions, while simultaneously enhancing whiteness by increasing the opacity of the glaze layer, resulting in a purer, brighter white for the final product.

However, to fully leverage these advantages, the quality requirements for magnesium carbonate raw materials are extremely stringent. Consistency in chemical composition is paramount; glaze formulations are precisely calculated chemical systems, and any batch variation will lead to instability in the glaze effect. The content of coloring impurities like iron and titanium must be extremely low, typically requiring Fe₂O₃ content below 0.05%; otherwise, adding magnesium carbonate would ironically introduce more yellowish tones, being counterproductive. Particle size distribution also needs to be controlled; excessively coarse particles can lead to incomplete decomposition during firing, causing bubbles or pinholes in the glaze surface.

The specialized magnesium carbonate provided by Hebei Messi Biology Co., Ltd. for the high-end ceramic industry is specifically developed to address these demanding requirements. Its products possess the following outstanding characteristics:

First, highly stable chemical composition with minimal batch-to-batch variation, providing a reliable raw material foundation for glaze formulation engineers and ensuring consistent color and texture in large-scale production.

Second, extremely high purity, with coloring impurities like iron and titanium controlled to very low levels (Fe₂O₃ < 0.03%), avoiding the introduction of external impurities, which is a prerequisite for achieving a high-white glaze surface.

Third, appropriate particle size; the product undergoes precise classification, ensuring both good suspension and dispersion in the glaze slurry and complete decomposition reaction within the glaze firing temperature range, without causing glaze surface defects.

From bone china tableware favored by the British Royal family to the sleek sanitary ware in top-tier hotels, Hebei Messi Biology’s high-purity magnesium carbonate is helping global ceramic manufacturers achieve their pursuit of perfect whiteness and exceptional quality. It is not merely a raw material in the modern ceramic industry, but an excellent example of the convergence of millennia-old kilning traditions and contemporary materials science, adorning every piece of ceramic art with its most magnificent “snow-white garment.”

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